Let \(\mathcal{C}\) be a maximal chain in \(2^{[n]}\) selected uniformly at random among all such chains. For each \(A\in 2^{[n]}\text{,}\) let \(1_A\) be the indicator function of the event that \(A\in\mathcal{C}\text{;}\) that is,
\begin{equation*}
1_A=\begin{cases}1\amp \text{ if } A\in\mathcal{C},\\ 0 \amp \text{ otherwise } . \end{cases}
\end{equation*}
Let \(\mathcal{A}\) be an antichain. For any choice of \(\mathcal{C}\text{,}\) we have
\begin{equation*}
\sum_{A\in \mathcal{A}}1_A = |\mathcal{A}\cap \mathcal{C}|\leq 1
\end{equation*}
\begin{equation*}
1\geq \mathbb{E}\left(\sum_{A\in \mathcal{A}}1_A\right) = \sum_{A\in \mathcal{A}}\mathbb{E}(1_A) = \sum_{A\in \mathcal{A}}\mathbb{P}(A\in\mathcal{C})\text{.}
\end{equation*}
Now, for any \(0\leq k\leq n\text{,}\) the chain \(\mathcal{C}\) contains exactly one element of \(\binom{[n]}{k}\text{,}\) and any such set is equally likely to be contained in \(\mathcal{C}\text{,}\) by symmetry. Therefore, for any \(A\subseteq [n]\text{,}\) it holds that
\begin{equation*}
\mathbb{P}(A\in\mathcal{C}) = \frac{1}{\binom{n}{|A|}}\text{.}
\end{equation*}
Putting these inequalities together completes the proof.